GCC toolchain: Add {SYSROOT} substitution with support for whitespaces

Any instance of {SYROOT} string in config's CFLAGS and LDFLAGS is replaced by sysroot path obtained from "gcc -print-sysroot"

*.pyc
**/__pycache__
.vscode
**/build/**
*.class
**/.svghmithumbs/**
**/my_*.der
**/my_*.pem
tests/tools/Docker/requirements.txt